JUCS - Journal of Universal Computer Science 29(4): 300-325, doi: 10.3897/jucs.90346
Application of Electronic Nose and Eye Systems for Detection of Adulteration in Olive Oil based on Chemometrics and Optimization Approaches
expand article infoSeyedeh Mahsa Mirhoseini-Moghaddam, Mohammad Reza Yamaghani, Adel Bakhshipour§
‡ Islamic Azad University, Lahijan, Iran§ University of Guilan, Rasht, Iran
Open Access
Abstract
In this study, a combined system of electronic nose (e-nose) and computer vision was developed for the detection of adulteration in extra virgin olive oil (EVOO). The canola oil was blended with the pure EVOO to provide adulterations at four levels of 5, 10, 15, and 20%. Data collection was carried out using an e-nose system containing 13 metal oxide gas sensors, and a computer vision system. Applying principal component analysis (PCA) on the e-nose-extracted features showed that 93% and 92% of total data variance was covered by the three first PCs generated from Maximum Sensor Response (MSR), Area Under Curve (AUC) features, respectively. Cluster analysis verified that the pure and impure EVOO samples can be categorized by e-nose properties. PCA-Quadratic Discriminant Analysis (PCA-QDA) classified the EVOOs with an accuracy of 100%. Multiple Linear Regression (MLR) was able to estimate the adulteration percentage with the R2 of 0.8565 and RMSE of 2.7125 on the validation dataset. Moreover, factor analysis using Partial Least Square (PLS) introduced the MQ3 and TGS2620 sensors as the most important e-nose sensors for EVOO adulteration monitoring. Application of Response Surface Methodology (RSM) on RGB, HSV, L*,a*, and b* as color parameters of the EVOO images revealed that the color parameters are at their optimal state in the case up to 0.1% of canola impurity, where the obtained desirability index was 97%. Results of this study demonstrated the high capability of e-nose and computer vision systems for accurate, fast and non-destructive detection of adulteration in EVOO and detection of food adulteration may be more reliable using these artificial senses. 
Keywords
Fraud detection, Machine learning, Volatile Matter, Image Processing, Optimization